http://www.totalsynthesis.eu/2008/08/total-synthesis-of-dodoneine/ Total Synthesis Blog - Organic Synthesis of Natural Products and related compounds Sat, 13 Mar 2010 14:26:45 +0000 hourly 1 http://wordpress.org/?v=3.3.1 http://www.totalsynthesis.eu/2008/08/total-synthesis-of-dodoneine/comment-page-1/#comment-303 zyp Sat, 28 Feb 2009 21:26:44 +0000 http://www.totalsynthesis.eu/?p=137#comment-303 Im a little bit surprised about the doublebound configuration. I´ve learned that under horner conditiones reaction is E-selective...on the other hand - i´ve never seen that CF3CO substituents on the P. I think under "normal" horner conditions there are just EtO substituents at P. Maybe thats the reason for the doublebound configuration...who knows :P Im a little bit surprised about the doublebound configuration. I´ve learned that under horner conditiones reaction is E-selective…on the other hand – i´ve never seen that CF3CO substituents on the P. I think under “normal” horner conditions there are just EtO substituents at P. Maybe thats the reason for the doublebound configuration…who knows

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